Different Modes of Anion Response Cause Circulatory Phase Transfer of a Coordination Cage with Controlled Directionality.

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ID: 2684
2019
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Ranked #60 of 192 articles by views in angewandte chemie (international ed in english)

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Abstract
Controlled directional transport of molecules is essential to complex natural systems, exemplified by cellular transport up to organismal circulatory systems. In contrast to these natural systems, synthetic systems that enable transport of molecules between several spatial locations on the macroscopic scale, when external stimuli are applied, remain to be explored. Here we report the transfer of a supramolecular cage with controlled directionality between three phases, based on the cage that responds reversibly in two distinct ways to different anions. Notably, circulatory phase transfer of the cage was demonstrated based on a system where the three layers of solvent are arranged within a circular track. The direction of circulation between solvent phases depended upon the order of addition of anions.
Reference Key
mihara2019differentangewandte Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Mihara, Nozomi;Ronson, Tanya K;Nitschke, Jonathan;
Journal angewandte chemie (international ed in english)
Year 2019
DOI
10.1002/anie.201906644
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Keywords Keywords not found

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