Direct allylic C–H alkylation of enol silyl ethers enabled by photoredox–Brønsted base hybrid catalysis
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ID: 26485
2019
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Abstract
Allylic C–H activation of enol silyl ethers via one-electron oxidation is usually accompanied by undesired desilylation. Here, under hybrid photoredox and Brønsted base catalysis, the authors show the mild functionalization of enol silyl ethers, providing a platform to access an array of complex carbonyl compounds.
| Reference Key |
ohmatsu2019directnature
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| Authors | Ohmatsu, Kohsuke;Nakashima, Tsubasa;Sato, Makoto;Ooi, Takashi; |
| Journal | Nature communications |
| Year | 2019 |
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| Keywords | Keywords not found |
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