Visible-light-triggered direct keto-difluoroacetylation of styrenes with (fluorosulfonyl)difluoroacetate and dimethyl sulfoxide leads to α-difluoroacetylated ketones.

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ID: 26443
2019
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Abstract
Photoredox-catalyzed direct keto-difluoroacetylation of styrenes with (fluorosulfonyl)difluoroacetate and dimethyl sulfoxide as an oxidant is disclosed. A variety of α-difluoroacetylated ketones bearing functional groups with good yields are obtained using fac-Ir(ppy)3 as a photocatalyst under visible light irradiation.
Reference Key
luo2019visiblelighttriggeredchemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Luo, Xuewei;Fan, Zhengning;Zhang, Bo;Chen, Chao;Xi, Chanjuan;
Journal Chemical communications (Cambridge, England)
Year 2019
DOI
10.1039/c9cc06037e
URL
Keywords Keywords not found

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