Organic Dye-Catalyzed, Visible-Light Photoredox Bromination of Arenes and Heteroarenes Using -Bromosuccinimide.

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ID: 26441
2018
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Abstract
A variety of arenes and heteroarenes are brominated in good to excellent yields using -bromosuccinimide (NBS) under mild and practical conditions. According to mechanistic investigations described within, the reaction is speculated to proceed via activation of NBS through a visible-light photoredox pathway utilizing erythrosine B as a photocatalyst. A photo-oxidative approach effectively amplifies the positive polarization on the bromine atom of the NBS reagent. This increase in the electrophilic nature of NBS results in drastically reduced reaction times and diversion from competing light-promoted reactive pathways.
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rogers2018organicacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Rogers, David A;Brown, Roxanne G;Brandeburg, Zachary C;Ko, Eric Y;Hopkins, Megan D;LeBlanc, Gabriel;Lamar, Angus A;
Journal ACS omega
Year 2018
DOI
10.1021/acsomega.8b02320
URL
http://dx.doi.org/10.1021/acsomega.8b02320
Keywords Keywords not found

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