crystal structure of (z)-3-(4-methoxybenzylidene)-2,3-dihydrobenzo[b][1,4]thiazepin-4(5h)-one
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ID: 259395
2015
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Abstract
In the title compound, C17H15NO2S, the two C atoms linking the S and carbonyl C atoms of the seven-membered thiazepine ring are disordered over two sites, with occupancies of 0.511 (4) and 0.489 (4); both disorder components adopt distorted twist-boat conformations. In the crystal, N—H...O and C—H...O hydrogen bonds link inverted-related molecules into dimers, incorporating R12(6) and R22(8) ring motifs; the acceptor carbonyl O atom is bifurcated. These dimers are further linked by C—H...O hydrogen bonds, forming supramolecular tapes running along the a axis.
| Reference Key |
vinayagam2015actacrystal
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|---|---|
| Authors | ;V. Vinayagam;J. Mohan Raj;S. Murugavel;R. Selvakumar;M. Bakthadoss |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S2056989014026267
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