crystal structure of tris[μ2-bis(diphenylphosphanyl)methane-κ2p:p′]di-μ3-bromido-trisilver(i) bromide–n,n′-phenylthiourea (1/1)
Clicks: 244
ID: 259315
2015
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This
article has not been analysed, so there is no overall score —
reader engagement is measured and shown alongside.
Reader Engagement
Steady Performance
30.0
/100
244 views
40 readers
AI Quality Assessment
Not analyzed
Readership in this journal
SteadyRanked #93 of 231 articles by views in Disability and rehabilitation
Most read
Least read
Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 231 in total.
Mint this article as an NFT
Not yet mintedCreate a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.
5
SUSD
one-off · no wallet required
Abstract
The title complex, [Ag3Br2(C25H22P2)3]Br·C7H8N2S, comprises a trinuclear [Ag3Br2(C25H22P2)3]+ unit, a Br− anion and one N,N′-dimethylthiourea molecule (ptu). Three AgI ions are linked via two μ3-bridging Br atoms, leading to a distorted triangular bipyramid with an Ag...Ag separation range of 3.1046 (6)–3.3556 (6) Å. The triangular Ag3 arrangement is stabilized by six P atoms from three chelating bis(diphenylphosphanyl)methane (dppm) ligands. The AgI ion presents a distorted tetrahedral coordination geometry. In the crystal, the bromide anion is connected to the ptu molecule through N—H...Br hydrogen bonds [graph-set motif R21(6)]. Each bromide/ptu aggregate links the complex ion via C—H...S and C—H...Br hydrogen bonds, leading to the formation of a three-dimensional network. Two phenyl rings from two dppm ligands were modelled as disordered over two sites.
| Reference Key |
nimthong-roldn2015actacrystal
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | ;Arunpatcha Nimthong-Roldán;Yupa Wattanakanjana;Jintana Rodkeaw |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S2056989015005150
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.