crystal structure and hirshfeld surface analysis of (e)-4-chloro-n-{2-[2-(4-nitrobenzylidene)hydrazin-1-yl]-2-oxoethyl}benzenesulfonamide n,n-dimethylformamide monosolvate

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ID: 259188
2018
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Abstract
The asymmetric unit of the title compound, C15H13ClN4O5S·C3H7NO, contains one molecule each of the Schiff base and the solvent dimethylformamide. The hydrazone group adopts an E configuration about the C=N bond. The dihedral angle between the two aromatic rings is 86.58 (2)°. In the crystal, pairs of N—H...O hydrogen bonds between centrosymmetrically related molecules generates rings with an R22(10) graph-set motif. The dimers are further linked via N—H...O and C—H...O hydrogen bonds, leading to the formation of R33(11) ring motifs. C—H...π interactions are also observed. The intermolecular interactions in the crystal structure were quantified and analysed using Hirshfeld surface analysis, which indicates that the most significant contacts in packing are O...H/H...O (31.3%), followed by H...H (25.4%) and C...H/H...C (13.0%).
Reference Key
purandara2018actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;H. Purandara;S. Foro;B. Thimme Gowda
Journal Disability and rehabilitation
Year 2018
DOI
10.1107/S205698901800292X
URL
http://scripts.iucr.org/cgi-bin/paper?S205698901800292X
Keywords
Hydrazone crystal structure inversion dimers intermolecular hydrogen bonds

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