thermodynamics of the complexation between salicylaldehyde thiosemicarbazone with cu2+ ion in methanol +1,4-dioxane binary solutions

Clicks: 291
ID: 257176
2014
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #28 of 151 articles by views in meditsinskaia radiologiia

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 151 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
The complexation reaction between salicylaldehyde thiosemicarbazone, abbreviated as STSC, with Cu2+ ion was studied in the binary mixtures of methanol + 1,4-dioxane binary by using UV-Visible spectrophotometric and conductometric methods at different temperatures. The formation constants (Kf) for the 1:1 complex, Cu2+-STSC, were calculated from computer fitting of the absorbance and molar conductance data against various mole ratios (cM:cL or cL:cM) in different binary solvent mixtures. A non-linear correlation was observed for the variation of logKf for the complex against the solvent compositions. Various thermodynamic parameters (ΔH, ΔS and ΔG) for the formation of Cu2+-STSC complex were also determined from the temperature dependence of the stability constants (Kf). The results showed that the complexation reaction is affected by the nature and composition of the mixed solvents.
Reference Key
rashmidipta2014journalthermodynamics Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Biswas Rashmidipta;Brahman Dhiraj;Sinha Biswajit
Journal meditsinskaia radiologiia
Year 2014
DOI
10.2298/JSC130730137B
URL
http://www.doiserbia.nb.rs/img/doi/0352-5139/2014/0352-51391300137B.pdf
Keywords
1 methanol cu2+ 4-dioxanechemistry

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.