les clusters moléculaires. applications en catalyse homogène et hétérogène molecular clusters. applications in homogeneous and heterogeneous catalysis
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Abstract
This article does not pretend to be an exhaustive bibliographic survey. It is merely a synthesis intended as an introduction to a sector of chemistry which is still young and especially is very vast and promising. Metal clusters are compounds made up of metal atours bonded together and generally surrounded by ligands. They have various characteristics of both mono-nuclear complexes and bulk metals. From a fundamental point of view, the chemistry of clusters is still a new and particularly vast field. From a practical point of view, the importance of clusters lies in the fact that a good number of them have shown proof of remarkable catalytic properties, both homogeneous and heterogeneous. They must henceforth be taken into consideration by chemical engineers because some of them may be involved in such important reactions as the Fischer-Troposch synthesis, the hydrogenation of olefins, the water-gas shift reaction, and the biological fixation of atmospheric nitrogen.
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m.2006oilles
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| Journal | addiction (abingdon, england) |
| Year | 2006 |
| DOI |
10.2516/ogst:1984028
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