crystal structure of {(r)-n2-[(benzo[h]quinolin-2-yl)methyl]-n2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine-κ4n,n′,n′′,n′′′}(trifluoromethanesulfonato-κo)zinc(ii)} trifluoromethanesulfonate dichloromethane 1.5-solvate

Clicks: 117
ID: 243806
2017
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Abstract
The zinc(II) atom in the title compound, [Zn(C48H31N4)(CF3SO3)](CF3SO3)·1.5CH2Cl2, adopts a distorted five-coordinate square-pyramidal geometry. It is coordinated by one trifluoromethanesulfonate ligand and four N atoms of the N2-[(benzo[h]quinolin-2-yl)methyl]-N2′-[(benzo[h]quinolin-2-yl)methylidene]-1,1′-binaphthyl-2,2′-diamine ligand. The complex is present as a single-stranded P-helimer monohelical structure incorporating π–π and/or σ–π interactions. One of the imine bonds present in the original ligand framework is reduced, leading to variations in bond lengths and torsion angles for each side of the ligand motif. The imine-bond reduction also affects the bond lengths involving the metal atom with the N-donor atoms located on the imine bond. There are two molecules of the complex in the asymmetric unit. One of the molecules exhibits positional disorder within the coordinating trifluoromethanesulfonate ion making the molecules symmetrically non-equivalent.
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skokan2017actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Shayna R. Skokan;Monica M. Reeson;Kayode D. Oshin;Anastasiya I. Vinokur;John A. Desper;Christopher J. Levy
Journal Disability and rehabilitation
Year 2017
DOI
10.1107/S2056989017008027
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989017008027
Keywords
crystal structure

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