crystal structure of catena-poly[[[aqualithium(i)]-μ-pyrimidine-2-carboxylato-κ4n1,o2:n3,o2′] hemihydrate]

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ID: 242508
2015
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Abstract
The title compound, {[Li(C5H3N2O2)(H2O)]·0.5H2O}n, comprises four symmetry-independent Li(C5H3N2O2)(H2O) units which form molecular ribbons running along the c-axis direction. Within each ribbon, the ligand molecule, acting in a μ2-mode, bridges two adjacent Li+ cations using both of its N,O-bonding sites. The coordination environment of each of the four Li+ cations can be described alternatively as either slightly distorted trigonal–bipyramidal or slightly distorted square–pyramidal. The ribbons are interconnected by a network of O—H...O hydrogen bonds.
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starosta2015actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Wojciech Starosta;Janusz Leciejewicz
Journal Disability and rehabilitation
Year 2015
DOI
10.1107/S2056989014026735
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989014026735
Keywords
crystal structure one-dimensional coordination polymer hydrogen bondingchemistry

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