disorder of lattice solvent molecules in the structure of hexaaqua(μ2-1,2,4,5-benzenetetracarboxylato)-bis(2,2’-dipyridylamine)dinickel(ii) hexahydrate dmso solvate
Clicks: 179
ID: 241982
2007
Article Quality & Performance Metrics
Overall Quality
Improving Quality
0.0
/100
Combines engagement data with AI-assessed academic quality
Reader Engagement
Emerging Content
3.3
/100
11 views
11 readers
Trending
AI Quality Assessment
Not analyzed
Abstract
The crystal structure of the complex [Ni2 (btc)(dipya)2(H2O)6]×6H2O·DMSO (btc = tetra-anion of 1,2,4,5-benzenetetracarboxylic acid, dipya = 2,2’-dipyridylamine) was refined in the triclinic system, space group P , using low temperature (170 K) X-ray diffraction data. The compound consists of binuclear complex entities and lattice solvent molecules making pseudo-layers parallel to the 101 plane and channels parallel to the b-axis. The observed structural features were compared with the previously reported results and formula [Ni2(btc)(dipya)2(H2O)6]×4H2O based on room temperature X-ray diffraction data. A possible arrangement of the disordered lattice solvent molecules located in the structural channels is described and discussed. It is concluded that the layout of these molecules is non-centrosymmetric, although the remaining and main part of the structure is centrosymmetric.
| Reference Key |
poleti2007journaldisorder
Use this key to autocite in the manuscript while using
SciMatic Manuscript Manager or Thesis Manager
|
|---|---|
| Authors | ;DEJAN POLETI;LJILJANA KARANOVIC;ALEKSANDAR KREMENOVIC;JELENA ROGAN |
| Journal | meditsinskaia radiologiia |
| Year | 2007 |
| DOI |
DOI not found
|
| URL | |
| Keywords |
Citations
No citations found. To add a citation, contact the admin at info@scimatic.org
Comments
No comments yet. Be the first to comment on this article.