crystal structure of ruthenium phthalocyanine with diaxial monoatomic ligand: bis(triphenylphosphine)iminium dichloro(phthalocyaninato(2-))ruthenium(iii)

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ID: 241973
2013
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Abstract
Axially-ligated iron phthalocyanines have been found to be good molecular conductors with giant negative magnetoresistance (GNMR) which originates from a strong intramolecular π-d interaction between the metal and phthalocyanine. Ab initio theoretical calculations showed that substitution of ruthenium into the phthalocyanine complex would result in a significant increase in the π-d interaction of the system, potentially intensifying GNMR. This paper presents the crystal preparation and X-ray structural characterization of bis(triphenylphosphine)iminium dichloro(phthalocyaninato(2-))ruthenium(III), PNP [RuIII(Pc2−)Cl2]. It is observed that [RuIII(Pc2−)Cl2] system has a symmetric planar RuPc unit with perpendicular axial ligands which results in a unidirectional and uniform solid-state arrangement, suitable for π-d interaction-based molecular conductors with potentially exceptional GNMR.
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yu2013journalcrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Derrick Ethelbhert Yu, Akira Kikuchi, Tetsuya Taketsugu, Tamotsu Inabe
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Journal british journal of psychology (london, england : 1953)
Year 2013
DOI
10.1155/2013/486318
URL
http://dx.doi.org/10.1155/2013/486318
Keywords
chemistry

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