crystal structure of catena-poly[1,3-dibenzylbenzimidazolium [[chloridomercurate(ii)]-di-μ-chlorido]]

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ID: 240488
2015
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Abstract
The asymmetric unit of the polymeric title compound, {(C21H19N2)[HgCl3]}n, comprises one-half of the cationic molecule, the other half being generated by application of twofold rotation symmetry, one Hg and two Cl atoms. The HgII atom, lying on a twofold rotation axis, exhibits a distorted triangular coordination environment and is surrounded by three Cl atoms with Hg—Cl distances in the range 2.359 (2)–2.4754 (13) Å. Two additional longer distances [Hg...Cl = 3.104 (14) Å] lead to the formation of polymeric [HgCl1/1Cl4/2]− chains extending along [001]. The crystal packing can be described by cationic layers alternating parallel to (-110) with the anionic chains located between the layers. The packing is consolidated by π–π stacking interactions between the benzene rings of the central benzimidazole entities, with centroid-to-centroid distances of 3.643 (3) Å.
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bouchouit2015actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Mehdi Bouchouit, Abdelmalek Bouraiou, Sofiane Bouacida, Hocine Merazig, Ali Belfaitah, Mebarek Bahnous
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Journal Disability and rehabilitation
Year 2015
DOI
10.1107/S2056989015023427
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989015023427
Keywords
crystal structure hydrogen-bond patternschemistry

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