Double-Helical Ag-S Rod-Based Porous Coordination Polymers with Double Activation: σ-Active and π-Active Functions.

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ID: 23771
2019
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Abstract
As common coinage metals, silver and silver compounds have very rich application in the organic catalytic reaction. Immobilization of silver compounds on heterogeneous media is the most common way used in industrial catalytic reactions. In this work, we designed and synthesized a new heterogeneous porous silver catalyst, with in situ-formed Ag-S rods as connecting nodes and thiosemicarbazide-functionalized linear ligands, used in both σ- and π-catalytic transformations. Strong Ag-S bonds bypassed the loss of noble silver elements and inhibited the formation of nonporous silver particles which always led to the decrease of yields in homogenous reactions. Furthermore, various derivatives of propargylamines and phenylacetylenes were applied as both σ and π-active substrates with moderate to good yields.
Reference Key
wang2019doublehelicalacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Wang, Xin;Chang, Zhiduo;Jing, Xu;He, Cheng;Duan, Chunying;
Journal ACS omega
Year 2019
DOI
10.1021/acsomega.9b00742
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