isokinetic parameters of thermal degradation of powder of [cd(n-boc-gly)2(h2o)2]n
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ID: 235307
2014
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Abstract
The coordination polymer [Cd(N-Boc-gly)2(H2O)2]n undergoes thermally induced
degradation in temperature region between 60 and 900oC. Kinetic parameters
were determined for dehydration (63-123oC) and further degradation processes
(123-461°C) using different isoconversional and non-isoconversional methods.
Due to appearance of kinetic “compensation effect”, isokinetic temperatures
were determined for individual degradation processes and correlated with
resonant vibrational frequencies ascribed to Cd-OH2 coordination bond, Cd-O
(O from N-Boc-glyH ligand) coordination bond and C-O covalent bond. [Projekat
Ministarstva nauke Republike Srbije, br. 172015]
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| Reference Key |
n.2014scienceisokinetic
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|---|---|
| Authors | ;Begović N.;Vasić M.M.;Grković A.;Blagojević V.A.;Minić D.M. |
| Journal | european romantic review |
| Year | 2014 |
| DOI |
10.2298/SOS1403323B
|
| URL | |
| Keywords |
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