crystal structure of μ-fluorido-bis{(η4-cyclooctadiene)[hexafluoridoantimonato(v)]platinum(ii)} hexafluoridoantimonate(v) hydrogen fluoride 0.75-solvate

Clicks: 97
ID: 232810
2016
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Steady

Ranked #209 of 231 articles by views in Disability and rehabilitation

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 231 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
In the complex cation of the binuclear solvated title salt, [Pt2F(SbF6)2(C8H12)2]SbF6·0.75HF, an F atom bridges the two platinum(II) atoms with a bond angle of 123.3 (2)°. The corresponding Pt—F bond lengths are in the range of other fluorine-bridged binuclear platinum(II) complexes. Two of the three SbF6− anions each coordinate with one F atom to one platinum(II) atom. Including the η4-bound cyclooctadiene (COD) ligands, the overall coordination sphere of each platinum(II) atom is square-planar. The third SbF6− anion is not bound to the complex. Hydrogen fluoride is present in the crystal structure as a solvent disordered over three positions, each with an occupancy of 0.25. F...F distances of 2.5512 (7), 2.6076 (8) and 3.2215 (10) Å to surrounding SbF6− anions are indicative of F—H...F hydrogen-bonding interactions although no H atoms could be localized for the disordered solvent molecules. The resulting hydrogen-bonded network is three-dimensional.
Reference Key
seppelt2016actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Konrad Seppelt;Roland Friedemann
Journal Disability and rehabilitation
Year 2016
DOI
10.1107/S2056989015022835
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989015022835
Keywords
crystal structure superacidchemistry

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.