Total Synthesis of Marine Natural Products Serinolamide A and Columbamide D.

Clicks: 328
ID: 23175
2019
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Abstract
In this report, an expeditious synthesis of two new biologically active marine natural products serinolamide A and columbamide D is documented. This convergent approach involves the key steps such as hydrolytic kinetic resolution, cross metathesis, Grignard reaction, Johnson-Claisen rearrangement, Mitsunobu, and so forth. Both of the target molecules were obtained from a common precursor ()- with high enantioselectivity, less synthetic steps, and in good overall yields (serinolamide A 66% and columbamide D 62%).
Reference Key
ghotekar2019totalacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Ghotekar, Ganesh S;Mujahid, Mohammad;Muthukrishnan, M;
Journal ACS omega
Year 2019
DOI
10.1021/acsomega.8b03417
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