Heterogeneously Catalyzed Pechmann Condensation Employing the Tailored ZnTiO NPs: Synthesis of Coumarin.

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ID: 23173
2019
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Abstract
A novel heterogeneous catalytic method was developed for the synthesis of coumarin and its derivatives using the Ti(IV)-doped ZnO matrix forming catalyst ZnTiO having a high surface area and good Lewis acidity. The catalyst shows high activity toward a broad spectrum of the substituted phenols with β-ketoesters such as ethyl acetoacetate, ethyl butyryl acetate, ethyl benzoyl acetate, and so forth in good yields over short reaction times during the synthesis of coumarins. The methodology was further extended for the synthesis of ayapin molecules. The catalyst also shows recycle activity up to seven cycles with very good stability.
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jadhav2019heterogeneouslyacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Jadhav, Nirajkumar H;Sakate, Sachin S;Rasal, Nishant K;Shinde, Dnyaneshwar R;Pawar, Ramdas A;
Journal ACS omega
Year 2019
DOI
10.1021/acsomega.9b00257
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