(+)-trans-chlorido{2-[(rp)-2-(methylsulfanyl)ferrocenyl]-2,5,6,7-tetrahydropyrrolo[1,2-c]imidazol-3-ylidene}bis(triphenylphosphane-κp)palladium(ii) hexafluoridophosphate dichloroform disolvate

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ID: 227034
2016
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Abstract
The title solvated complex, [FePd(C5H5)(C12H13N2S)Cl(C18H15P)2]PF6·2CHCl3, bearing a chiral ferrocenyl pyrroloimidazolylidene N-heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloroimidazolium salt to Pd(PPh3)4. The PdII ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom trans to the coordinating C atom of the pyrroloimidazolylidene ligand. The complex features a pendant thioether group that is not involved in coordination to Pd. In the crystal, weak C—H...F and C—H...π interactions connect the components of the structure, forming chains propagating along [1-10]. The fused pyrrolidine ring is in an envelope conformation, and the flap atom was refined as disordered over two sets of sites, with occupancies of 0.77 (4) and 0.23 (4).
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wilson-konderka2016acta(+)-trans-chlorido{2-[(rp)-2-(methylsulfanyl)ferrocenyl]-2,5,6,7-tetrahydropyrrolo[1,2-c]imidazol-3-ylidene}bis(triphenylphosphane-p)palladium(ii) Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Cody Wilson-Konderka;Alan J. Lough;Costa Metallinos
Journal Disability and rehabilitation
Year 2016
DOI
10.1107/S2056989016013190
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989016013190
Keywords
crystal structure n-heterocyclic carbene thioether palladium pyrroloimidazoliumchemistry

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