Aqua(4-hydroxypyridine-2,6-dicarboxylato)(1,10-phenanothroline)copper(II) 4.5-hydrate
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2008
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Abstract
The title compound, [Cu(C7H3NO5)(C12H8N2)(H2O)]·4.5H2O or [Cu(hypydc)(phen)(H2O)]·4.5H2O (phen is 1,10-phenanthroline and hypydcH2 is 4-hydroxypyridine-2,6-dicarboxylic acid), was obtained by the reaction of copper(II) nitrate hexahydrate with the proton-transfer compound (phenH)2(hypydc) in aqueous solution. Both the cationic and the anionic fragments of the proton-transfer compound are involved in complexation. Each CuII atom has a distorted octahedral geometry. It is hexacoordinated by three O atoms and three N atoms, from one phen fragment (as bidentate ligand), one (hypydc)2− unit (as tridentate ligand) and a water molecule. In the crystal structure, O—H...O and C—H...O hydrogen bonds, and π–π stacking interactions [centroid-to-centroid distance 3.5642 (11) Å] between the phen ring systems, contribute to the formation of a three-dimensional supramolecular structure.
| Reference Key |
aghabozorg2008aqua4hydroxypyridine26dicarboxylato110phenanothrolinecopperiiacta
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| Authors | Aghabozorg, Hossein;Motyeian, Elham;Soleimannejad, Janet;Ghadermazi, Mohammad;Gharamaleki, Jafar Attar; |
| Journal | acta crystallographica section e |
| Year | 2008 |
| DOI |
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| Keywords | Keywords not found |
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