estudio del mecanismo de compensación de batio3 dopado con la2o3
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Abstract
En este trabajo se estudió la incorporación del ión La3+ en la red de BaTiO3. Se comprobó que bajas concentraciones de La3+ inhiben el crecimiento de los granos de BaTiO3 significativamente, a la vez que originan un material altamente densificado. Sin embargo, se confirmó que existe un límite de concentración de La2O3 a partir del cual se observó un retardo en el sinterizado del BaTiO3. La incorporación de La3+ como donor en el BaTiO3 modificó su estructura de defectos, favoreció la formación de vacantes de titanio y lo estabilizó en una fase pseudocúbica. Este efecto también se refleja en las propiedades dieléctricas del material y en la temperatura de transición de fases cúbica-tetragonal.
| Reference Key |
s.2004boletnestudio
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| Authors | ;Castro, M. S.;Brzozowski, E.;Ramajo, M. |
| Journal | medicinal chemistry (shariqah (united arab emirates)) |
| Year | 2004 |
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