crystal structure of n-[(methylsulfanyl)carbonyl]urea
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ID: 220413
2016
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Abstract
The almost planar (r.m.s. deviation = 0.055 Å) title compound, (MeS)C(O)NHC(O)NH2, was formed during an attempted crystallization of dimethyl cyanocarbonimidodithioate with CrO2Cl2; an unexpected redox reaction converted the cyanocarbonimido moiety to a urea group and removed one methylthiol group. In the crystal, hydrogen-bonding interactions from the amide and amido N—H groups to carbonyl O atoms of neighbouring molecules result in [010] ribbon-like chains.
| Reference Key |
diop2016actacrystal
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|---|---|
| Authors | ;Mouhamadou Birame Diop;Libasse Diop;Allen G. Oliver |
| Journal | Disability and rehabilitation |
| Year | 2016 |
| DOI |
10.1107/S2056989016002322
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