one-pot synthesis of cu(ii) complex with partially oxidized ttf moieties
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ID: 220095
2012
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Abstract
The one-pot synthesis of a Cu(II) complex with partially oxidized tetrathiafulvalene (TTF) moieties in its capping MT-Hsae-TTF ligands, [CuII(MT-sae-TTF)2] [CuICl2] was realized by the simultaneous occurrence of Cu(II) complexation and CuIICl2 mediated oxidation of TTF moieties. The crystal structure was composed of one-dimensional columns formed by partially oxidized TTF moieties and thus the cation radical salt showed relatively high electrical conductivity. Tight binding band structure calculations indicated the existence of a Peierls gap due to the tetramerization of the TTF moieties in the one-dimensional stacking column at room temperature, which is consistent with the semiconducting behavior of this salt.
| Reference Key |
oshio2012crystalsone-pot
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| Authors | ;Hiroki Oshio;Takuya Shiga;Kiyotaka Mitsumoto;Ryosuke Kitabatake;Hiroyuki Nishikawa |
| Journal | turk kardiyoloji dernegi arsivi |
| Year | 2012 |
| DOI |
10.3390/cryst2030935
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