crystal structures of bis[4-(dimethylamino)pyridinium] tetrakis(thiocyanato-κn)manganate(ii) and tris[4-(dimethylamino)pyridinium] pentakis(thiocyanato-κn)manganate(ii)

Clicks: 293
ID: 216451
2018
Free PDF
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Emerging

Ranked #75 of 231 articles by views in Disability and rehabilitation

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 231 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
The crystal structures of the title salts, (C7H11N2)2[Mn(NCS)4] (1) and (C7H11N2)3[Mn(NCS)5] (2), consist of manganese(II) cations that are tetrahedrally (1) or trigonal–bipyramidally (2) coordinated to four or five terminal N-bonded thiocyanate ligands, respectively, into discrete anionic complexes. The negative charge is compensated by two (1) or three (2) 4-(dimethylamino)pyridinium cations, which are protonated at the pyridine N atom. The asymmetric unit of compound 1 consists of one anionic complex and two 4-(dimethylamino)pyridinium cations, whereas that of compound 2 consists of two anionic complexes and six 4-(dimethylamino)pyridinium cations, all of them located in general positions. These complexes are linked by N—H...S, C—H...S and C—H...N hydrogen-bonding interactions between the 4-(dimethylamino)pyridinium cations and the thiocyanate ligands into three-dimensional network structures.
Reference Key
neumann2018actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Tristan Neumann, Inke Jess, Christian Näther
Are you one of these authors? Claim your profile
Journal Disability and rehabilitation
Year 2018
DOI
10.1107/S2056989017017510
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989017017510
Keywords
crystal structure hydrogen bonding Cobalt hydrogen bondingchemistry nickelchemistry

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.