synthesis and thermoelectric properties of ni-doped zrcosb half-heusler compounds
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ID: 211231
2018
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Abstract
The Ni-doped ZrCo1−xNixSb half-Heusler compounds were prepared by arc-melting and spark plasma sintering technology. X-ray diffraction analysis results showed that all samples were crystallized in a half-Heusler phase. Thermoelectric properties of ZrCo1−xNixSb compounds were measured from room temperature to 850 K. The electrical conductivity and the absolute value of Seebeck coefficient increased with the Ni-doping content increasing due to the Ni substitution at Co. sites. The lattice thermal conductivity of ZrCo1−xNixSb samples was depressed dramatically because of the acoustic phonon scattering and point defect scattering. The figure of merit of ZrCo1−xNixSb compounds was improved due to the decreased thermal conductivity and improved power factor. The maximum ZT value of 0.24 was achieved for ZrCo0.92Ni0.08Sb sample at 850 K.
| Reference Key |
zhao2018metalssynthesis
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|---|---|
| Authors | ;Degang Zhao;Lin Wang;Lin Bo;Di Wu |
| Journal | seminars in cancer biology |
| Year | 2018 |
| DOI |
10.3390/met8010061
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| URL | |
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