crystal structure of poly[[μ2-diaqua-diaqua-μ2-l-proline-κ2o:o′-strontium] dibromide]
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ID: 211147
2015
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Abstract
In the title coordination polymer, {[Sr(C5H9NO2)(H2O)4]Br2}n, the proline molecule exists in a zwitterionic form with one of the ring C atoms disordered over two sites [site-occupancy factors = 0.57 (6):0.43 (6)]. The SrII ion is nine-coordinated by six water O atoms, two monodentate and two μ2-bridging, and three carboxylate O atoms of the proline ligands, with two bridging [Sr—O range = 2.524 (4)–2.800 (5) Å]. In the crystal, there is no direct interaction between the proline molecules. However, the proline and water molecules associate with the bromide counter-anions through a number of intermolecular O—H...Br and N—H...Br hydrogen-bonding interactions, giving a three-dimensional supramolecular structure.
| Reference Key |
sathiskumar2015actacrystal
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|---|---|
| Authors | ;Selladurai Sathiskumar;Thangavelu Balakrishnan;Kandasamy Ramamurthi;Subbiah Thamotharan |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S2056989015017302
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