Molecular Engineering and Structure-Related Properties of Squaraine Dyes Based on the Core and Wings Concept.

Clicks: 202
ID: 20730
2018
Article Quality & Performance Metrics
Overall Quality
Not rated
Combines reader engagement with the AI quality analysis. This article has not been analysed, so there is no overall score — reader engagement is measured and shown alongside.
AI Quality Assessment
Not analyzed
Readership in this journal
Steady

Ranked #359 of 475 articles by views in ACS omega

Most read Least read

Bar heights use a square-root scale. Only the 120 most-read articles are drawn; the journal has 475 in total.

Mint this article as an NFT
Not yet minted

Create a permanent, verifiable on-chain record of this article on the Scimatic Network. The NFT is held in your Journament account, and you can withdraw it to your own wallet at any time.

5 SUSD one-off · no wallet required
Sign in to mint
Abstract
Three new squaraine-based functional π-conjugated molecules were synthesized considering the core and wings concept. The molecules, , , and , were end-capped with three different wings, such as malononitrile, 2-(3-hexyl-4-oxothiazolidin-2-ylidene)malononitrile, and 3-ethyl-2-thioxothiazolidin-4-one. Among the three dyes, showed the highest molar extinction coefficient. The photoluminescence of all the dyes showed an opposite trend to that of the absorption maximum. The electrochemical results showed that the lowest unoccupied molecular orbital level of all the dyes ranged from -3.72 to -3.82 eV, whereas the highest occupied molecular orbital ranged from -4.89 to -4.94 eV. Solvatochromism was carried out to observe the effects of the solvent containing the dyes. The electronic structure of the dyes was examined using simulations. The dyes were characterized theoretically, and the red-shifted absorption of was explained and correlated with its biradicaloid character and singlet-triplet energy gap.
Reference Key
rao2018molecularacs Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Rao, G Hanumantha;Rana, Prem Jyoti Singh;Chitumalla, Ramesh Kumar;Jang, Joonkyung;Singh, Surya Prakash;
Journal ACS omega
Year 2018
DOI
10.1021/acsomega.8b01809
URL
Keywords Keywords not found

Citations

No citations found. To add a citation, contact the admin at info@scimatic.org

Comments

No comments yet. Be the first to comment on this article.