crystal structures of 1-(4-chlorophenyl)-2-(diphenylphosphoryl)ethan-1-one and 1-(diphenylphosphoryl)-3,3-dimethylbutan-2-one

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ID: 206550
2015
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Abstract
The title compounds, C20H16ClO2P, (I), and C18H21O2P, (II), were synthesized via an Arbuzov reaction between an α-bromoketone and isopropoxydiphenylphosphane. In the crystals of both compounds, molecules are linked via bifurcated C—H...(O,O) hydrogen bonds, forming chains propagating along [100] for (I) and along [010] for (II). The chains are linked via C—H...π interactions, leading to the formation of sheets lying parallel to (010) for (I) and (001) for (II). The absolute structure of compound (II) was determined by resonant scattering [Flack parameter = 0.088 (14)].
Reference Key
leach2015actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Erin G. Leach;Alyssa A. Kulesza;Richard J. Staples;Shannon M. Biros
Journal Disability and rehabilitation
Year 2015
DOI
10.1107/S2056989015006994
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989015006994
Keywords
crystal structure π interactionschemistry

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