decachlorocyclopentasilanes coordinated by pairs of chloride anions, with different cations, but the same solvent molecules
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ID: 203940
2017
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Abstract
We have determined the crystal structures of two decachlorocyclopentasilanes, namely bis(tetra-n-butylammonium) dichloride decachlorocyclopentasilane dichloromethane disolvate, 2C16H36N+·2Cl−·Si5Cl10·2CH2Cl2, (I), and bis(tetraethylammonium) dichloride decachlorocyclopentasilane dichloromethane disolvate, 2C8H20N+·2Cl−·Si5Cl10·2CH2Cl2, (II), both of which crystallize with discrete cations, anions, and solvent molecules. In (I), the complete decachlorocyclopentasilane ring is generated by a crystallographic twofold rotation axis. In (II), one cation is located on a general position and the other two are disordered about centres of inversion. These are the first structures featuring the structural motif of a five-membered cyclopentasilane ring coordinated from both sides by a chloride ion. The extended structures of (I) and (II) feature numerous C—H...Cl interactions. In (II), the N atoms are located on centres of inversion and as a result, the ethylene chains are disordered over equally occupied orientations.
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moxter2017actadecachlorocyclopentasilanes
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| Authors | ;Maximilian Moxter;Julian Teichmann;Hans-Wolfram Lerner;Michael Bolte;Matthias Wagner |
| Journal | Disability and rehabilitation |
| Year | 2017 |
| DOI |
10.1107/S2056989017016310
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