crystal structure of catena-poly[[[aquabis(1h-imidazole-κn3)copper(ii)]-μ-3-({4-[(2-carboxylatoethyl)carbamoyl]phenyl}formamido)propanoato-κ2o:o′] dihydrate]
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ID: 203219
2015
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Abstract
In the title polymeric complex, {[Cu(C14H14N2O6)(C3H4N2)2(H2O)]·2H2O}n, the CuII cation, located on a twofold rotation axis, is coordinated by one water molecule and two imidazole molecules as well as two symmetry-related 3-([4-[(2-carboxylatoethyl)carbamoyl]phenyl]formamido)propanoate dianions (L2−) in an approximately square-pyramidal geometry. The coordinating water molecule is located on a twofold rotation axis while the L2− anion sits about an inversion center. The L2− anions bridge the CuII cations, forming polymeric chains propagating along the [101] direction. In the crystal, O—H...O, N—H...O hydrogen bonds and weak C—H...π interaction link the polymeric chains and the solvent water molecules into a three-dimensional supramolecular architecture.
| Reference Key |
liu2015actacrystal
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|---|---|
| Authors | ;Yan Liu;Liu-Yang Xu;Hong-Tao Zhang |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S205698901500626X
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| URL | |
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