comparative ebulliometry: a simple, reliable technique for accurate measurement of the number average molecular weight of macromolecules. preliminary studies on heavy crude fractions Ébulliométrie comparative : technique simple et fiable pour déterminer précisément la masse molaire moyenne en nombre des macromolécules. etudes préliminaires sur des fractions lourdes de bruts

Clicks: 263
ID: 202808
2006
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Ranked #40 of 124 articles by views in addiction (abingdon, england)

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Abstract
This article is divided into two parts. In the first part, the authors present a comparison of the major techniques for the measurement of the molecular weight of macromolecules. The bibliographic results are gathered in several tables. In the second part, a comparative ebulliometer for the measurement of the number average molecular weight (Mn) of heavy crude oil fractions is described. The high efficiency of the apparatus is demonstrated with a preliminary study of atmospheric distillation residues and resins. The measurement of molecular weights up to 2000 g/mol is possible in less than 4 hours with an uncertainty of about 2%.
Cet article comprend deux parties. Dans la première, les auteurs présentent une comparaison entre les principales techniques de détermination de la masse molaire de macromolécules. Les résultats de l'étude bibliographique sont rassemblés dans plusieurs tableaux. La seconde partie décrit un ébulliomètre comparatif conçu pour la mesure de la masse molaire moyenne en nombre (Mn) des fractions lourdes des bruts. Une illustration de l'efficacité de cet appareil est indiquée avec l'étude préliminaire de résidus de distillation atmosphérique et de résines. En particulier, la mesure de masses molaires pouvant atteindre 2000 g/mol est possible en moins de 4 heures avec une incertitude expérimentale de l'ordre de 2 %.
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Authors ;Behar E.;Barreau A.;Vellut D.;Jose J.
Journal addiction (abingdon, england)
Year 2006
DOI
10.2516/ogst:1998072
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