Modification of chitosan macromolecule and its mechanism for the removal of Pb(II) ions from aqueous environment

Clicks: 216
ID: 19905
2019
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Ranked #156 of 200 articles by views in International journal of biological macromolecules

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Abstract
It is well-known that heavy metals are non-biodegradable and have been showing remarkable impacts on the environment, public health and economics. Because of high toxic tendency, lead (Pb), is one of the foremost considerable hazardous metal with high environmental impacts. Chitosan is a polysaccharide, and can be utilized in wastewater treatment because of its good sorption ability. Amino and hydroxyl groups (C-3 position) on chitosan can serve as electrostatic interaction and complexation sites for metal cations. Chemical crosslinking can effectively enhance the stability of chitosan in acidic media. Hence a novel, cost-effective and eco-friendly ZnO incorporated into aminated chitosan Schiff's base (ACSSB@ZnO) has been synthesized, characterized (BET, XRD, FTIR, SEM, TEM and H NMR), and utilized as an adsorbent for the removal of Pb(II) ions from the aqueous environment. The various operating parameters, such as pH (2-8), agitation speed (30-180), adsorbent dose (0.1-0.8 g), contact time (0-140 min), metal ion concentration and temperature (303-323 K) were investigated. The maximum sorption capacity of Pb(II) onto ACSSB@ZnO was found to be 55.55 mg/g. The equilibrium, and kinetic studies suggested that the adsorption process followed the Langmuir isotherm and Pseudo-Second-Order model. Thermodynamic data showed that the sorption process was feasible, spontaneous, and endothermic.
Reference Key
yuvaraja2019modificationinternational Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Yuvaraja, G.
Journal International journal of biological macromolecules
Year 2019
DOI
10.1016/j.ijbiomac.2019.06.016
URL
Keywords Keywords not found

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