crystal structure of (±)-[trans-cyclohexane-1,2-diylbis(azanediyl)]diphosphonium dibromide dichloromethane disolvate
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ID: 198640
2016
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Abstract
The cation of the title solvated salt, C42H42N2P22+·2Br−·2CH2Cl2, lies on a crystallographic twofold rotation axis. The 1,2-diaminocyclohexane fragment has a chair conformation with two N atoms in a transoid conformation [N—C—C—N = 163.4 (2)°]. In the crystal, the cations are linked to the anions by N—H...Br and C—H...Br hydrogen bonds, forming a chain structure along the c axis. The dichloromethane molecule takes part in the hydrogen-bond network through C—H...π and C—H...Br interactions.
| Reference Key |
lvarez2016actacrystal
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|---|---|
| Authors | ;Aurora Rodríguez Álvarez;Hugo Tlahuext;Jean-Michel Grévy |
| Journal | Disability and rehabilitation |
| Year | 2016 |
| DOI |
10.1107/S2056989016004576
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