an examination of the electron densities in a series of tripodal cobalt complexes bridged by magnesium, calcium, strontium, and barium †

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ID: 197760
2018
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Abstract
X-ray crystallographic and theoretical charge-density data for a series of compounds—[(Co(Ts3tren))M(Co(Ts3tren))], (M = Mg, Ca, Sr and Ba)—were examined. The crystal structures were isostructural, and the alkaline-earth-metal ions had the same six-coordinate environment oxygen donor atoms which was octahedral despite the large variation in their ionic radii. The isomorphism of these molecules was surprising, and a theoretical examination of their electronic structures, with various metal ions along the series, provided detailed insight into their stabilities. The theoretical and experimental data were consistent and agreed well. The local properties of the Co(II) ion and its donor atoms were relatively independent of the alkaline earth metals.
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bacsa2018crystalsan Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;John Bacsa;Lillian G. Ramírez-Palma;Fernando Cortés-Guzmán;Christian M. Wallen;Christopher C. Scarborough
Journal turk kardiyoloji dernegi arsivi
Year 2018
DOI
10.3390/cryst8060234
URL
http://www.mdpi.com/2073-4352/8/6/234
Keywords Keywords not found

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