crystal structure of ag2(μ-scn)2(nh3)4

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ID: 197460
2016
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Abstract
Di-μ-thiocyanato-bis[diamminesilver(I)], [Ag2(μ-SCN)2(NH3)4], was synthesized by the reaction of AgSCN with anhydrous liquid ammonia. In the binuclear molecule, the AgI atom is coordinated by two ammine ligands and the S atom of one thiocyanate ligand. Two of these [Ag(SCN)(NH3)2] units are bridged by the S atoms of the thiocyanate anions at longer distances, leading to a dimer with point group symmetry C2. The distance between the AgI atoms in the dimer is at 3.0927 (6) Å within the range of argentophilic interactions. The crystal structure displays N—H...N and N—H...S hydrogen-bonding interactions that build up a three-dimensional network.
Reference Key
mller2016actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Thomas G. Müller;Florian Kraus
Journal Disability and rehabilitation
Year 2016
DOI
10.1107/S2056989016008823
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989016008823
Keywords
crystal structure ammonia

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