the first homoleptic complex of seven-coordinated osmium: synthesis and crystallographical evidence of pentagonal bipyramidal polyhedron of heptacyanoosmate(iv)
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ID: 195520
2016
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Abstract
The ligand exchange in (n-Bu4N)2OsIVCl6 (n-Bu4N = tetra-n-butylammonium) leads to the formation of the osmium(IV) heptacyanide, the first fully inorganic homoleptic complex of heptacoordinated osmium. The single-crystal X-ray diffraction (SC-XRD) study reveals the pentagonal bipyramidal molecular structure of the [Os(CN)7]3− anion. The latter being a diamagnetic analogue of the highly anisotropic paramagnetic synthon, [ReIV(CN)7]3− can be used for the synthesis of the model heterometallic coordination compounds for the detailed study and simulation of the magnetic properties of the low-dimensional molecular nanomagnets involving 5d metal heptacyanides.
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peresypkina2016crystalsthe
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| Authors | ;Eugenia V. Peresypkina;Anatolie Gavriluta;Kira E. Vostrikova |
| Journal | turk kardiyoloji dernegi arsivi |
| Year | 2016 |
| DOI |
10.3390/cryst6090102
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