thermal, electrical, and optical properties of synthesized (1e, 2e)-(4-bromophenyl)(hydroxyimino)acetaldehyde oxime complexes
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ID: 193766
2013
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Abstract
The (1E, 2E)-(4-bromophenyl)(hydroxyimino)acetaldehyde oxime complexes, [ML2], M = Co(II), Cu(II), and Ni(II), were synthesized and characterized by elemental analysis, magnetic susceptibility, FT-IR spectra, and thermal analysis techniques. The optical band gap of this ligand and its complexes were determined by UV-vis spectrophotometer in the wavelength range 300–800 nm. A decrease in the energy band gap of the [CoL2], [NiL2], and [CuL2] complexes has been observed compared with LH ligand. Temperature-dependent conductivity measurements showed that all samples behave like semiconductor. Activation energies calculated from Arrhenius plots showed that the conduction occurs via both intramolecular and the intermolecular processes.
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karapinar2013journalthermal,
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| Authors | ;Emin Karapinar;Orhan Karabulut;Nazan Karapinar |
| Journal | british journal of psychology (london, england : 1953) |
| Year | 2013 |
| DOI |
10.1155/2013/256983
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