crystal structure of bis(2,2′-bipyridine-κ2n,n′)bis(thiocyanato-κn)manganese(ii) 2,2′-bipyridine monosolvate

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ID: 189934
2015
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Abstract
In the crystal structure of the mononuclear title compound, [Mn(NCS)2(C10H8N2)2]·C10H8N2, the MnII cation is coordinated in an all-cis configuration by two N-bound thiocyanate anions and two 2,2′-bipyridine ligands within a slightly distorted octahedral environment. The asymmetric unit consists of one MnII cation, two thiocyanate anions and two 2,2′-bipyridine ligands, as well as two non-coordinating 2,2′-bipyridine ligands that are each located on centres of inversion. In the crystal structure, the discrete [Mn(NCS)2(C10H8N2)2] complex molecules are arranged in such a way that cavities are formed, in which the solvent 2,2′-bipyridine molecules are located. Apart from van der Waals forces, there are no remarkable intermolecular interactions present in the crystal structure.
Reference Key
suckert2015actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Stefan Suckert;Inke Jess;Christian Näther
Journal Disability and rehabilitation
Year 2015
DOI
10.1107/S205698901402516X
URL
http://scripts.iucr.org/cgi-bin/paper?S205698901402516X
Keywords
2 crystal structure coordination polymer nickel(ii) complex hydrogen bondingchemistry dimethylpyrazinechemistry

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