crystal structure of bis[2-(1h-benzimidazol-2-yl)aniline]silver(i) nitrate

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ID: 184096
2015
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Abstract
In the cation of the title salt, [Ag(C13H11N3)2]NO3, the AgI atom lies on a crystallographic inversion center and is coordinated by four N atoms from two bidentate 2-(1H-benzimidazol-2-yl)aniline ligands in a distorted square-planar geometry. The Ag—N(aniline) bond [2.729 (2) Å] is significantly longer than the Ag—N(imidazole) bond [2.165 (1) Å]. In the ligand, the aniline ring is twisted by 37.87 (6)° from the mean plane of the benzimidazole ring system. The nitrate anion lies on a crystallographic twofold rotation axis which passes through the N atom and one of the O atoms. In the crystal, N—H...O hydrogen bonds link the components, forming a layer parallel to the bc plane.
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Authors ;Yongtae Kim;Sung Kwon Kang
Journal Disability and rehabilitation
Year 2015
DOI
10.1107/S2056989015015315
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989015015315
Keywords
2 crystal structure hydrogen bonding benzimidazole one-dimensional coordination polymer zinc complex hydrogen bondschemistry hydrogen bondingchemistry benzothiazolphenol

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