ca4as3 – a new binary calcium arsenide
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ID: 182980
2015
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Abstract
The crystal structure of the binary compound tetracalcium triarsenide, Ca4As3, was investigated by single-crystal X-ray diffraction. Ca4As3 crystallizes in the Ba4P3 structure type and is thus a homologue of isotypic Sr4As3. The unit cell contains 32 Ca2+ cations, 16 As3− isolated anions and four centrosymmetric [As2]4– dumbbells. The As atoms in each of the dumbbells are connected by a single bond, thus this calcium arsenide is a Zintl phase.
| Reference Key |
hoffmann2015actaca4as3
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|---|---|
| Authors | ;Andrea V. Hoffmann;Viktor Hlukhyy;Thomas F. Fässler |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S2056989015022367
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