molecular clips based on the crown ethers: prospective receptors for the sr2+cations removal

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ID: 178587
2015
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Abstract
Strontium cation complexation with diphenylglycoluril-based molecular clips containing 12-crown-4, 15-crown-5, 18-crown-6 and 21-crown-7 residues was qualitatively studied by FAB mass-spectrometry. It was found that at low concentrations of Sr2+ cations molecular clip with fragments of 15-crown-5 is the most effective, and it is assumed that it is due to the formation of the most stable «sandwich-type» complex. The higher removal degree with an excess of Sr2+ cations is observed in the case of molecular clips with fragments of 18-crown-6 due to the formation of 1:2 composition complexes.
Reference Key
lyapunov2015vsnikmolecular Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;A. Yu. Lyapunov
Journal Nature communications
Year 2015
DOI
10.18524/2304-0947.2014.3(51).40403
URL
http://heraldchem.onu.edu.ua/article/view/52-59
Keywords Keywords not found

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