crystal structure of bis(η5-cyclopentadienyl)(2,3-diethylbutane-1,4-diyl)hafnium(iv)

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ID: 175702
2015
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Abstract
The title compound, [Hf(C5H5)2(C8H16)], proves a structural motif of hafnacyclopentane besides the coordination of two cyclopentadienyl ligands in an η5-fashion. The hafnacyclopentane ring has a twist conformation and is substituted by two ethyl groups in the β,β′-positions, which are trans orientated to each other. One cyclopentadienyl ring and one ethyl group are each disordered over two positions with site-occupancy ratios of 0.679 (15):0.321 (15) and 0.702 (18):0.298 (18), respectively.
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burlakov2015actacrystal Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors Vladimir V. Burlakov, Wolfgang Baumann, Perdita Arndt, Anke Spannenberg, Uwe Rosenthal
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Journal Disability and rehabilitation
Year 2015
DOI
10.1107/S2056989014026929
URL
http://scripts.iucr.org/cgi-bin/paper?S2056989014026929
Keywords
crystal structure

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