dynamic processes in prochiral solvating agents (pro-csas) studied by nmr spectroscopy
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2014
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Abstract
Several dynamic processes, including tautomerism and macrocyclic inversion, in 1H-NMR prochiral solvating agents (pro-CSAs) are investigated. Various features of pro-CSA, including modes of interaction for complex formation, stoichiometry, binding strength and temperature effects were compared for three representative pro-CSA molecules. Structural effects of conjugated tetrapyrrole pro-CSA on the mechanism of enantiomeric excess determination are also discussed. Detailed analysis of species (complexes) and dynamic processes occurring in solution and their 1H-NMR spectral manifestations at various temperatures is presented.
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labuta2014symmetrydynamic
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| Authors | ;Jan Labuta;Shinsuke Ishihara;Katsuhiko Ariga;Jonathan P. Hill |
| Journal | journal of hospitality and tourism management |
| Year | 2014 |
| DOI |
10.3390/sym6020345
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