1-{[(e)-(4-{[(2z)-2,3-dihydro-1,3-thiazol-2-ylidene]sulfamoyl}phenyl)iminiumyl]methyl}naphthalen-2-olate
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ID: 174824
2015
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Abstract
In the title zwitterionic compound, C20H15N3O3S2, the 2-hydroxynaphthalene-1-carbaldehyde group A, the anilinic unit B and the 1,3-thiazol-2(3H)-imine group C are each approximately planar with r.m.s. deviation of 0.0721, 0.0412 and 0.0125 Å, respectively. The dihedral angles between A/B, A/C and B/C are 24.70 (10), 79.97 (7) and 83.14 (6)°, respectively. There is an intramolecular S(6) motif involving the imine N—H and the naphtholate O atom. In the crystal, inversion-related molecules form dimers as a result of N—H...N and N—H...O hydrogen bonds with R22(8) and R12(4) motifs, respectively. Weak π–π interactions between the benzene and naphthyl rings of inversion-related molecules have ring centroid–centroid distances of 3.638 (2) and 4.041 (2) Å. A C—H...π interaction occurs between the thiazol ring and the benzene ring of an adjacent molecule.
| Reference Key |
shahid2015acta1-{[(e)-(4-{[(2z)-2,3-dihydro-1,3-thiazol-2-ylidene]sulfamoyl}phenyl)iminiumyl]methyl}naphthalen-2-olate
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|---|---|
| Authors | ;Muhammad Shahid;Muhammad Nawaz Tahir;Muhammad Salim;Munawar Ali Munawar;Hazoor Ahmad Shad |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S2056989015009640
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| URL | |
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