synthesis of framework isomer mofs containing zinc and 4-tetrazolyl benzenecarboxylic acid via a structure directing solvothermal approach
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2015
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Abstract
The solvothermal synthesis of framework isomers was carried out using the hybrid carboxylate and tetrazolate functional ligand, 4-tetrazolyl benzenecarboxylic acid (H2TBC, TBC = 4-tetrazolyl benzenecarboxylate) and zinc. H2TBC was also synthesized with the solvothermal approach, and is referred herein as structure 1. Using single-crystal X-ray diffraction, we found that the tetrazolate groups of TBC show an unusual “opposite-on” coordination mode with zinc. Three previously characterized metal-organic frameworks (MOFs) were obtained by systematically changing the solvents of the H2TBC-Zn reaction, (1) ZnTBC, 2, which has a non-porous structure; (2) Zn2(TBC)2(H2O), 3, which has an amphiphilic pore structure and (3) Zn2(TBC)2{guest}, 4, which is porous and has channels containing uncoordinated N heteroatoms. Fluorescence spectra of 4 reveal a strong blue emission mainly from the TBC ligands.
| Reference Key |
ordonez2015crystalssynthesis
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|---|---|
| Authors | ;Carlos Ordonez;Tiffany L. Kinnibrugh;Hongwu Xu;Jennifer Lindline;Tatiana Timofeeva;Qiang Wei |
| Journal | turk kardiyoloji dernegi arsivi |
| Year | 2015 |
| DOI |
10.3390/cryst5020193
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| URL | |
| Keywords | Keywords not found |
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