frame transformation relations and symmetry analysis of fluxional symmetric rotor dimers
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ID: 166952
2013
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Abstract
The theory of Frame transformation relations between the states of Born Oppenheimer and the weak coupling approximations is developed for polyatomic molecules. The symmetry relations are a generalization of the frame transformation relations derived by Harter and Crogman for coupled rotor molecules. A key internal symmetry label (named “soul”) is defined so that it remains a constant label for frame transformation relations, and is conserved during vibronic transitions, ionization, and even dissociation provided the nuclear spin-rotation interaction is relatively small. Simplified procedures are given for obtaining selection rules, statistical weights, and matrix elements of multipole operators for common molecules having various point symmetries.
| Reference Key |
harter2013symmetryframe
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|---|---|
| Authors | ;William G. Harter;Harrison B. Chen;Bumgyunmiga Choi;Horace T. Crogman |
| Journal | journal of hospitality and tourism management |
| Year | 2013 |
| DOI |
10.3390/sym5010086
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