electrochemical study of diphenyl ether derivatives used as herbicides

Clicks: 173
ID: 161949
2011
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Abstract
The electrochemical behaviour of five nitro diphenyl ethers used as herbicides is investigated in acetonitrile. A detailed study by cyclic voltammetry and exhaustive electrolysis is carried out for the anodic oxidation of 2-Chloro-6-nitro-3-phenoxyaniline (aclonifen) and shows that the major oxidation product is a dimeric compound. A mechanistic scheme involving a coupling process is postulated for the electrochemical oxidation of this compound. Furthermore, the use of differential pulse voltammetry on a glassy carbon electrode permits the selective determination of aclonifen. The limit of detection is 0.6 μg/mL.
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zaouak2011internationalelectrochemical Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Amira Zaouak;Fatma Matoussi;Mohamed Dachraoui
Journal BMJ open quality
Year 2011
DOI
10.4061/2011/904570
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