crystal structure of 4-(dimethylamino)pyridinium cis-diaquabis(oxalato-κ2o,o′)ferrate(iii) hemihydrate
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ID: 157820
2015
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Abstract
The FeIII ions in the hybrid title salt, (C7H11N2)[Fe(C2O4)2(H2O)2]·0.5H2O, show a distorted octahedral coordination environment, with four O atoms from two chelating oxalate dianions and two O atoms from two cis aqua ligands. The average Fe—O(oxalate) bond length [2.00 (2) Å] is shorter than the average Fe—O(water) bond length [2.027 (19) Å]. The ionic components are connected via intermolecular N—H...O and O—H...O hydrogen bonds into a three-dimensional network.
| Reference Key |
djomo2015actacrystal
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|---|---|
| Authors | ;Edith Dimitri Djomo;Frédéric Capet;Justin Nenwa;Michel M. Bélombé;Michel Foulon |
| Journal | Disability and rehabilitation |
| Year | 2015 |
| DOI |
10.1107/S2056989015013213
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