zinc oxide: connecting theory and experiment

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ID: 155205
2013
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Abstract
Zinc oxide (ZnO) is a material with a great variety of industrial applications including high heat capacity, thermal conductivity and temperature stability. Clearly, it would be of great importance to find new stable and/or metastable modifications of zinc oxide, and investigate the influence of pressure and/or temperature on these structures, and try to connect theoretical results to experimental observations. In order to reach this goal, we performed several research studies, using modern theoretical methods. We have predicted possible crystal structures for ZnO using simulated annealing (SA), followed by investigations of the barrier structure using the threshold algorithm (TA). Finally, we have performed calculations using the prescribed path algorithm (PP), where connections between experimental structures on the energy landscape, and in particular transition states, were investigated in detail. The results were in good agreement with previous theoretical and experimental observations, where available, and we have found several additional (meta)stable modifications at standard, elevated and negative pressures. Furthermore, we were able to gain new insight into synthesis conditions for the various ZnO modifications and to connect our results to the actual synthesis and transformation routes.
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zagorac2013processingzinc Use this key to autocite in the manuscript while using SciMatic Manuscript Manager or Thesis Manager
Authors ;Dejan Zagorac;Johann Christian Schön;Jelena Zagorac;Ilya Vladimirovich Pentin;Martin Jansen
Journal preventive veterinary medicine
Year 2013
DOI
10.2298/PAC1303111Z
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